Degree Of Chemical Weathering Research Articles

Rare-earth element (REE) remobilization and fractionation in bauxites zones from sedimentary kaolin deposits, western Georgia (USA), Upper Coastal Plain

Rare-earth elements (REE) are critical minerals that are indispensable for high-tech products and technologies. Significant efforts have been focused on the exploration and identification of new and domestic reserves of REE. This study reports geochemical and mineralogical occurrences of accumulated REE with significant fractions of ion-adsorption clays (IAC) within bauxite-kaolin ore, hosted within sedimentary strata. This deposit type can be found throughout portions of Georgia and eastern Alabama (USA) in the Southeast Upper Coastal Plain. These deposits were developed by high degrees of chemical weathering of older, kaolinite-rich sedimentary strata. Several major changes in whole rock mineralogy and geochemistry occurred, leading to the development of zones of REE depletion, fractionation, and accumulation. Depletions of REE in the bauxite zone were significant, with whole rock contents of ~50% ΣREE relative to average upper continental crust (UCC). Fractionated REE were observed by low La/YbN values (La/YbN = 0.2) due to depletion in LREE (<40% UCC) with concomitant HREE retention (~1.1–1.3 times UCC). Strongly positive Ce/Ce* anomalies (Ce/Ce* = 1.3), very low ion-exchangeable Ce contents (Ce/LREE = 0.1), and low solubility of Ce (0.9–1.2%) under reducing conditions compared to all other LREE (4.5–9.9%) were further observed. These characteristics were strong indications of REE fractionation that occurred during formation of the bauxite zone. Underlying the bauxite zone, accumulations of the remobilized REE were substantial. At the base of the lower kaolin zone, elevated ion-exchangeable REE contents were notable (11–33% for total REE), and more specifically 11–12% for LREE, ~28% for ΣTb-Lu, and ~ 33% for Y. The elevated ion-exchangeable contents coincided with whole rock contents that were ~ 250% ΣREE relative to UCC. These REE accumulations occurred within organic-rich strata at the base of the section. This setting represents a significant difference relative to the REE accumulations in profiles for the granite-regolith deposit type. These findings highlighted the movement of dissolved REE, accumulation as sorbed species, as well as the potential role that organic ligands play during REE precipitation and sorption processes. These results permit consideration for further research into REE occurrences in clay deposits of sedimentary origin, which have been underexplored compared to granite-regolith REE deposits.

Identification of the Sedimentary Sources and Origin of Uranium for Zhiluo Formation of the Tarangaole U Deposit, Northeastern Ordos Basin

The large-sized Tarangaole uranium deposit and its neighboring Daying and Nalinggou deposits, located in the northeastern margin of the Ordos Basin, constitutes a major uranium resource base in northern China. In order to further clarify the sedimentary material source, uranium source and regional sediment–tectonic setting of the uranium-fed clastic rocks (i.e., Zhiluo Formation(J2z)) in the district, this paper carried out whole-rock geochemistry, heavy minerals composition and in situ U-Pb dating of detrital zircons for sandstones from the lower section of the Zhiluo Formation. The results have shown that the average chemical differentiation index (CIA) for the host rocks is 73.16 and the chemical weathering degree is moderate. Heavy minerals are mainly composed of ilmenite, garnet, chlorpyrite, zircon, pyrite, apatite, hematite, etc. The U-Pb dating of detrital zircon generally indicates three age peaks, i.e., 260~Ma, 1850~Ma and 2450~Ma, respectively. In conclusion, the source rocks may have been formed at active continental margins, e.g., in a continental margin arc environment. The sedimentary materials mainly come from khondalite series, TTGs, granulite, and mafic–ultramafic intrusive rocks distributed among the Daqing–Ula Mountains and adjacent areas, etc. The Late Paleozoic U-rich intermediate and acidic magmatic rocks spreading over the eastern part of the Ula–Daqing and Wolf mountains have provided the main uranium sources for the formation of major U deposits in the northern Ordos Basin.

Schmidt-hammer R-values from glacially-scoured bedrock surfaces across glacier-foreland boundaries: Insights into Holocene weathering rates with implications for exposure-age dating

Schmidt-hammer R-values were measured on glacially-scoured bedrock outcrops located inside and outside of 11 ‘Little Ice Age’ glacier-foreland boundaries in the Jotunheimen and Jostedalsbreen regions of southern Norway. Analysing paired samples differing in exposure age by ~10,000 years constitutes a field experiment on chemical weathering rates within and between regions. Mean R-values (± 95 % confidence intervals) from inside sites were 65.9 ± 0.6 and 66.9 ± 0.6 for rock surfaces composed of pyroxene-granulite gneiss in Jotunheimen at altitudes of 990–1360 m above sea level and granite and granitic gneiss in the Jostedalsbreen region at 270–620 m a.s.l. The corresponding values from outside sites of 39.9 ± 0.9 and 39.0 ± 0.9 were significantly lower, indicating a higher degree of chemical weathering. In contrast, regional differences in mean R-values were insignificant. A similar pattern is reflected in indices of rock weathering (39.0 % for Jotunheimen and 41.6 % for Jostedalsbreen), and weathering rate (2.8 R-value units and 3.0 units per 1000 years, respectively). These results imply an estimated minimum age resolution of Schmidt-hammer exposure-age dating of ~265–315 years and a maximum age range of ~20,000 years. They suggest potential application of the Schmidt hammer to both studies of weathering rates and exposure-age dating at the regional scale, despite lithological variation associated with different rock types and climatic variation associated with altitudinal differences of up to 1000 m between the sites.

Controls on the formation of Mn carbonates in mudrocks of the Datangpo Formation, Northern Margin Rift Basin, Yangtze Block

Deglaciation following the Sturtian Ice Age led to widespread manganese carbonate precipitates within marine mudrocks, reflecting unique climatic and oceanographic changes. The Mn carbonates hold economic importance in the Datangpo Formation, Yangtze Block, South China. Although their genesis in the Nanhua Rift Basin is well understood, little is known regarding their formation mechanism in the North Margin Rift Basin (NMRB). With growing interest in Mn ore exploration in this region, this study examines the weathering trend, climate patterns and watermass conditions using a variety of geochemical proxies. The results reveal two phases of climate variation during the deglaciation. Climate during the early phase (Phase I) was unstable, characterized by fluctuating values of Chemical Index of Alteration (CIA = 65 ± 4) and elevated Li isotope (8.8 ± 3.0‰) patterns. The degree of chemical weathering during the later stage (Phase II) was relatively stable (CIA = 65 ± 1, δ7Li = 5.4 ± 2.7‰), but the weathering intensity increased due to the reduced denudation rate, possibly related to a shift in the basin development. Fe speciation data indicate euxinia prevailing much of the section. However, Mo and U enrichment (> 1) and fluctuating ratios of Mo versus total organic content (0–40) suggest that pulses of freshwater influx associated with climate variation during Phase I caused the fluctuation of the chemocline along the continental shelf, facilitating the formation of Mn carbonates through the particulate Fe-Mn-hydroxide shuttle. With the establishment of stabilized climate, basin tectonics, and watermass circulation during Phase II, the accumulation of Mn carbonates in the sediments became less significant. The accumulation of Mn carbonates in the NMRB conforms to the “bathtub ring model”, distinct from the metallogenic model in the NRB, providing valuable guidance for Mn ore prospecting within this area and elsewhere with similar settings.

Sedimentological and geochemical evaluation of sandstones of the Ilaro formation, Dahomey Basin, Southwestern Nigeria : Insights into paleoenvironments, provenance, and tectonic settings

Grain size analysis, geochemistry, and petrography of sandstones of the Ilaro Formation exposed at the Ajegunle area were investigated to infer provenance, transportation history, tectonic setting, paleoenvironment, and degree of palaeoweathering of the sediments. Selected sandstones were analyzed, and the major, trace, and rare earth elements were determined using Inductively Coupled Plasma Mass Spectrometry (ICP-MS). Results from the granulometric analysis showed that sandstones were deposited in fluvial conditions. The sandstones exhibit a coarse-grained texture, displaying poor sorting and being texturally immature. The petrographic analysis indicated that quartz was predominant, whereas opaque minerals, muscovite, and ferruginous ground mass were present in smaller quantities. The sandstones can be geochemically classified as arkose and subarenite. The sandstones have an average composition of SiO2 (82.87%) and Al2O3 (9.49%), while K2O, Na2O, MgO, CaO, and P2O5 have &lt;1% each. The elevated Al2O3 content is associated with the lithic fragment composition, whereas the low concentrations of MgO (mean 0.03%), Na2O (mean 0.008%), and K2O (mean 0.04%) suggest chemical destruction in an oxidizing environment. The angularity of the grains indicated a short transportation history very close to the provenance. Bivariate and discriminant plots from major elements and trace elements suggest the sandstones were non-marine and sourced from intermediate rocks. The sandstones were deposited in an oxic-dyoxic condition under a humid climate and passive or active continental margins. The average values of the weathering indices indicate an intense degree of chemical weathering.

Geochemical and mineralogical characteristics of shales from the early to middle Permian Dohol Formation in Peninsular Malaysia: Implications for organic matter enrichment, provenance, tectonic setting, palaeoweathering and paleoclimate

The early to middle Permian Dohol Formation is characterized by a significant presence of shale deposits. While these shales exhibit a low potential to generate hydrocarbons, there is a need to ascertain the possible reasons for the low hydrocarbon generation potential. Also, there are several unidentified properties and attributes associated with these shales in terms of their inorganic geochemical characteristics and their mineralogy. This study is focused on using XRF, ICPMS, and SEM with EDX to determine the mineralogical and geochemical characteristics of these shales and use these data to discuss their provenance history and tectonic setting and interpret the paleoclimatic and paleoweathering conditions. The inorganic geochemical analysis shows that the shales from the Dohol Formation are from a felsic igneous source. The shales were also identified to be from a passive margin based on the bivariate plot of SiO2 vs log (K2O/Na2O) and several multidimensional diagram plots. The CIA and CIW data, as well as the A–CN–K plot, all point to a significant degree of chemical weathering, ranging from mild to intense. The Sr/Cu ratio and C-value, combined with various other geochemical proxies, indicate that the shales were formed in warm-humid climatic conditions. The SEM analysis shows that the samples are mainly composed of kaolinite and illite, and this result was supported by the EDX elemental composition. The high terrigenous influx of sediments, the oxic to sub-oxic conditions in which the sediments were deposited, and finally low marine productivity were found to be the reasons for the low TOC in the shales from the Dohol Formation.

Tungsten stable isotope composition of the upper continental crust

Tungsten (W) stable isotope data for twenty-four composites made from the fine-grained matrix of glacial diamictites, deposited between the Mesoarchean and the Paleozoic, as well as two Archean tonalite-trondhjemite-granodiorites (TTG) are used to refine the W isotope compositions (expressed as δ186W deviations from the NIST 3163 W standard) of the upper continental crust (UCC). To do this we evaluate W isotope fractionation in the diamictites as the result of both magmatic and low-temperature processes. The δ186W values of the diamictites are heterogeneous (0.017 ± 0.011 ‰, 2SE to 0.182 ± 0.007 ‰, 2SE), encompassing the range of previously published values for igneous rocks. We find that δ186W correlates positively with the diamictite’s chemical index of alteration (CIA), a measure of the degree of chemical weathering in the provenance, suggesting that the continental regolith (i.e., surface material composed of weathered residues) is isotopically heavy for W. Since W in rivers and ocean water is also isotopically heavy, this suggests that equilibration with Fe-Mn-oxides controls the W isotope composition of surface waters and that such oxides are not important constituents of the regolith, whose W is likely accommodated in clays. Using diamictites with low CIA (<60, n = 9), we calculate an average δ186W of 0.046 ± 0.036 ‰ (2SD) for the UCC, from 2.3 to 0.3 Ga. This average is combined with the TTG data of this study, as well as data from the literature for upper crustal rocks to obtain a representative δ186W value of the UCC of 0.046 ± 0.046 ‰ (2SD). The W stable isotope composition of the UCC is lighter than that of mantle-derived melts (MORB and OIB, with an average δ186W = 0.082 ± 0.026 ‰, 2SD), and much lighter than the weighted average δ186W of intra-oceanic arcs (δ186W = 0.104 ± 0.052 ‰, 2SD), though the spread in the arc rocks is large. The significant difference in δ186W between average intra-oceanic island arc lavas and UCC is intriguing given that continental crust is thought to form primarily via arc magmatism. This difference suggests that not all modern intra-oceanic arcs are representative of those that formed the continental crust. Rather, only arcs that are enriched in incompatible trace elements, which also tend to have lighter W isotope compositions, may have been involved in making new continental crust. Alternatively, there may have been a secular change in the W isotope composition of arc magmas.

Cross-shelf processes of terrigenous organic matter drive mercury speciation on the east siberian shelf in the Arctic Ocean

The cross-shelf distributions of total mercury (THg), methylmercury (MeHg) and organic and inorganic matter, as well as the presence of the hgcA gene were investigated on the East Siberian Shelf (ESS) to understand the processes underlying the speciation of sedimentary Hg. Samples were collected from 12 stations grouped into four zones based on water depth: inner shelf (5 stations), mid-shelf (3 stations), outer shelf (2 stations), and slope (2 stations). The THg concentration in the surface sediment increased from the inner shelf (0.25 ± 0.023 nmol g−1) toward the slope (0.52 nmol g−1), and, when normalized to total organic carbon content, the THg showed a positive correlation with the clay-to-sand ratio (r2 = 0.48, p = 0.012) and degree of chemical weathering (r2 = 0.79, p = 0.0001). The highest MeHg concentrations (3.0 ± 1.8 pmol g−1), as well as peaks in the S/C ratio (0.012 ± 0.002) of sediment-leached organic matter, were found on the mid-shelf, suggesting that the activities of sulfate reducers control the net Hg(II) methylation rates in the sediment. This was supported by results from a principal component analysis (PCA) performed with Hg species concentrations and sediment-leached organic matter compositions. The site-specific variation in MeHg showed the highest similarity with that of CHONS compounds in the PCA, where Deltaproteobacteria were projected to be putative Hg(II) methylators in the gene analysis. In summary, the hydrodynamic sorting of lithogenic particles appears to govern the cross-shelf distribution of THg, and in situ methylation is considered a major source of MeHg in the ESS sediment.

Genetic implications of Th/U, Th/K, and U/K ratios for U mineralizations: A case study from El-Missikat and El-Erediya shear zones, Eastern Desert, Egypt

The current work is an attempt to reveal the possible utilization of the radiometric measurements to build-up a complete genetic scenario for magmatic, hydrothermal, and supergene uranium mineralization. For this purpose, ground gamma-ray survey was performed through the exploratory tunnels dug perpendicular to El-Missikat and El-Erediya shear zones, the Central Eastern Desert of Egypt. Contents of U, Th, and K were measured for the host pink granite (e.g., avg.15.94 U ppm, 35.62 Th ppm, and 6.63% K), alteration zones (brecciation, silicification, greisenization, kaolinization and hematitization) (e.g., avg. 124.01 U ppm, 63.67 Th ppm, and 3.13% K), and mineralized silica veins (e.g., avg. 312.65 U ppm, 92.22 Th ppm, and 2.62% K). All of these data were graphically represented as correlation plots of Th vs. U, Th/U vs. U, Th vs. K, and U/K vs. Th/K. The overall results indicate magmatic, hydrothermal, and supergene sources of El-Missikat and El-Erediya U mineralization. The magma-derived U contents are enclosed mainly in the pink granite that is mostly characterized by normal Th/U (2.5–5) and Th/K ratios (3–5*10–4). The hydrothermal processes through the alteration zones and mineralized silica veins are reflected by the weak correlation of Th with U (e.g. r = 0.13 and − 0.39), the strong negative correlation of Th/U ratio with U (e.g. r = − 0.82), 2.5˃Th/U˃0.1, Th/K˃5*10–4, Th/K < 3*10–4, and the strong positive correlation of U/K with Th/K (e.g. r = 0.91) as well as the occurrence of thorite, columbite, xenotime and hydrothermal zircon (0.5 > Th/U ≤ 0.1). Afterwards, the hydrothermal mineralization underwent some degrees of chemical weathering that resulted in supergene U mineralization whose fingerprints can be traced by the occurrence of secondary U minerals (e.g. kasolite and uranophane), Th/U ratios ≤ 0.1, and the weak correlation between Th/K and U/K (e.g. r = 0.39 and − 0.11).

Petrology and geochemistry of sandstone from Lower Cretaceous Kikhla Formation, NW Libya: Implications for provenance and depositional setting.

This study aims to determine and investigate the provenance of the source rocks and the depositional setting of the Kikhla Formation, northwestern Libya. It is mainly composed of mature quartzitic sandstone alternating with conglomerate and clay. The study proved that the sandstone is yellow-white in color and commonly carries quartz granular and small fragments of silicified wood. The environmental deposition is under differing fluvial conditions and by a large braided river. Texturally, the Kikhla sandstone is poorly cemented, coarse to very coarse grained and strongly unimodal and is classified as litharenite and subarkose by the modal composition, which is supported by geochemical studies. According to petrography and geochemistry, the Kikhla sandstone was deposited in a passive continental margin basin, mainly from granitic sources. On the basis of major elements ratios, and petrographic interpretation, the source rocks are most likely recognized as Proterozoic granites that were exposed via rifting. The CIA values (73.28-93.97) indicate a high degree of chemical weathering, which could be attributed to the arid climate conditions in the source area and mainly controlled by the source-rock provenance, hydraulic sorting during transport and deposition, diagenesis and depositional environment. According to chemical investigations, sandstone exhibits significant concentrations of SiO2, Na2O&gt; K2O, and Fe2O3, which is compatible with the modal data.

Radiometric and magnetic susceptibility characterization of soil profiles: Geophysical data and their relationship with Antarctic periglacial processes, pedogenesis, and lithology

Maritime Antarctica is still pedologically unexplored by proximal geophysical sensors. In-depth soil geophysical characterizations in depth can provide comprehensive information regarding how weathering, pedogenesis, and periglacial processes operate in periglacial environments, with advantages like non-invasive methodology, fast and precise data acquisition, practical equipment operation, and cost-effectiveness. This research aimed to carry out the first proximal gamma-spectrometric and magnetic geophysical characterization of soil profiles in maritime Antarctica and to relate the geophysical variables analyzed with periglacial processes, weathering, pedogenesis, geology, and landscape dynamics. The study was carried out in the Keller Peninsula (King George Island, Maritime Antarctica) with the pedological characterization of soil profiles, using two proximal geophysical sensors (gamma spectrometer and susceptibility meter) that quantify, respectively, soil radionuclides uranium, thorium and potassium as well as soil magnetic susceptibility. For that, twenty soil profiles were described and characterized, and soil samples were collected for physico-chemical analysis. In addition, readings were carried out with the two geophysical sensors in each soil profile, through soil horizons up to the lithic contact and/or permafrost top. We performed exploratory statistical analyses in R software as follows: visualizing the geophysical variables in soil depth for each profile and soil class, obtaining descriptive statistics among soil classes, analyzing geophysical variables by geology and soil classes, performing Spearman correlation between geophysical variables and soil physico-chemical attributes, and applying principal component analysis to pedological classes, geophysical variables, and soil physico-chemical attributes. The results showed that radionuclide contents increased with soil profile depth in all profiles and soil classes analyzed, except for Cryosols where permafrost is present, and cryoturbation was more pronounced. The potassium content was high in all soil profiles, evidencing the low degree of chemical weathering and leaching. The soil magnetic susceptibility values tended to decrease in depth, mainly where permafrost was present. The gravel content contributed more to the levels of radionuclide content. The clay content in some soil classes present contributed secondarily to uranium and thorium contents. Soil profiles located on marine terraces were influenced by periglacial reworking and deposition of different materials, showing increases in magnetic susceptibility values with soil depth by the absolute accumulation of ferrimagnetic minerals. Principal component analyses efficiently separated Regosols from other soil classes by soil κ related to lithology, whereas Cambisols and other soil classes were separated by radionuclide contents related to incipient pedogenesis. These findings may give new insights into understand this inhospitable continent.

Chemical weathering detection in the periglacial landscapes of Maritime Antarctica: New approach using geophysical sensors, topographic variables and machine learning algorithms

The chemical weathering intensity in Antarctica is underestimated. As the chemical weathering intensity increases, hydrological, geochemical and geophysical changes occur in the different environmental spheres and at their interfaces through reactions and energy flows. Thus, once chemical weathering rates are understood and estimated, they can be used to predict and assess changes and trends in different environmental spheres. Few studies on the chemical weathering intensity have been performed in Antarctica. We used radiometric and magnetic properties associated with terrain attributes and the chemical degree of alteration of the igneous rock to model the chemical weathering intensity in Maritime Antarctica by using machine learning. Then, we related the chemical weathering intensity and geophysical variables with periglacial processes. To do this, gamma-spectrometric and magnetic readings were carried out using proximal-field sensors at 91 points located on different lithologies in a representative area of Maritime Antarctica. A qualitative analysis of chemical alteration for the different lithologies was carried out based on field observations and rock properties, and the levels of the chemical weathering degree were established. The geophysical data associated with terrain attributes were used as input data in the modeling of the weathering intensity. Then, the levels of the rock weathering degree were used as the “y” variable in the models. The results indicated that the C5.0 algorithm had the best performance in predicting the weathering intensity, and the most important variables were eTh, 40K, 40K/eTh, 40K/eU, the magnetic susceptibility and terrain attributes. The contents of radionuclides and ferrimagnetic minerals in different lithologies, concomitantly with the intensity at which chemical weathering occurs, determine the contents of these elements. However, the stability and distribution of these elements in a cold periglacial environment are controlled by periglacial processes. The chemical weathering intensity prediction model using gamma-spectrometric and magnetic data matched the in situ estimate of the chemical degree of alteration of the rock. The pyritized andesites showed the highest intensities of weathering, followed by tuffites, diorites, andesitic basalts and basaltic andesites, and the lowest weathering intensity was shown by undifferentiated marine sediments. This work highlighted the suitability of using machine learning techniques and proximal-field sensor data to study the chemical weathering process on different rocks in these important and inhospitable areas of the cryosphere system.

Influence of hydrothermal and upwelling events on organic matter accumulation in the gas-bearing lower Cambrian shales of the middle Yangtze Block, South China

With onoing studies on the diversification of animals during the early Cambrian in the Yangtze Block, resource effects associated with environmental changes have started to be elucidated, in which regional sedimentary events might have played an important role. The gas-rich Yichang area in the southern Huangling anticline is a potential area for shale gas development and provides a more suitable target for unravelling the debates on organic matter (OM) accumulation in the Low Cambrian marine black shales. This study integrated elemental geochemical and mineralogy time-series analyses based on core samples drilled in Yichang area on the shallow-water platform to constrain the evolution of the depositional environments and consider the forcing function behind OM enrichment in the Shuijinguo Formation. Distinctive TOC and Cu/Al peaks within the black shale deposited in the Shuijingtuo Member I suggest intensification of bioproductivity level. The chemical index of alteration (CIA), regarded as an indicator of paleoclimatic variation, increased in the upsection, and together with increasing Sr/Cu and quartz/feldspar ratio values, suggest a trend toward warming conditions and a moderate degree of chemical weathering. The geochemical proxies for the degree of water mass restriction (Mo/TOC and Co × Mn) and paleoredox (MoEF, UEF, U/Th and Corg/P) indicate that the shallow-water shelf experienced weakly-to moderately-restricted water conditions under an anoxic/euxinic environment in the Shuijingtuo Member I and transited to a moderately-restricted water mass with suboxic conditions during the late Shuijingtuo and Shipai periods. A positive Eu anomaly within the Shuijingtuo Member I provided robust evidence of hydrothermal activity. We propose here for an opening of deposition conditions on the shallow-water platform which results in enhanced upwelling and hydrothermal activity (Si, Ba, et.), thereby ultimately disrupting the original nutrient cycling for the metabolism and prompting the OM accumulation in the epicontinental sea during the early Cambrian.

Quantitative estimates of Holocene precipitation from aeolian sand-palaeosol sequences across the Ordos Plateau, northern China, based on surface soil geochemistry

Quantitative precipitation reconstructions are important for studies of past Earth surface processes and for predicting future trends, especially in the semi-arid region of northern China, where the dune fields landscape is dominated by shifts of the Asian summer monsoonal boundary. However, the relationships between desert deposits and climatic factors are controversial and it remains unclear how these relationships can be used for quantitative paleoenvironmental reconstruction. We investigated the relationship between the degree of chemical weathering of surface soil, quantified using the Chemical Index of Alteration (CIA) and modern climatic variables, along transects across the Ordos Plateau. The relationship was then used to obtain quantitative estimates of Holocene mean annual precipitation (MAP) from aeolian sand-palaeosol sequences in this region. The results reveal that MAP is the dominant climatic variable controlling the chemical weathering of surface soil, accounting for ∼ 69–91% of the total explained variance. This robust relationship enabled us to establish a regional CIA-based transfer function to reconstruct the MAP. This relationship was confirmed by a study of Holocene climate change and chemical weathering of aeolian sequences across the Ordos Plateau, which indicated that paleo-precipitation explained ∼ 76–88% of the total explained variance. The reconstruction demonstrates that the MAP was respectively ∼ 60–103 mm and ∼ 21–63 mm lower in the early and late Holocene than the modern MAP, while it was ∼ 34–77 mm (∼20–30%) higher in the middle Holocene than the modern MAP. Our results also demonstrate the latitudinal zonality of MAP evolution across the Ordos Plateau during the mid-Holocene. Overall, our findings provide new insights into the chemical weathering of surface soils and the response of Holocene aeolian deposits to climate change, and they confirm the utility of a geochemical proxy for quantitative environmental reconstruction in the semi-arid desert region of northern China.

Chemical weathering intensity controls the accumulation of nickel in rice (Oryza sativa L.) cultivated in basalt-derived paddy fields

Globally, a high concentration of nickel (Ni) in agricultural soil is closely related to basalt weathering. Rice grains readily accumulate Ni, however, the evolution of Ni distribution and mobility in paddy fields with basalt weathering remain unclear. This study investigated the distribution, geochemical fraction, and mobilization of Ni in basalt bedrock-paddy soil-rice plant continuums under contrasting climates through a combination of field surveys, chemical extractions, X-ray diffraction, and scanning electron microscopy-energy dispersive X-ray spectroscopy (SEM-EDS) analyses. Results show that the soils developed in tropical climates were more enriched in Ni than those in temperate climates. The concentration of Ni in rice grains from the studied temperate regions (3.71 ± 2.01 mg/kg) was higher than that in the tropical regions (0.57 ± 0.37 mg/kg). The concentration of Ni bound to Fe (hydro)oxides in paddy soils from temperate regions was five times higher than that in tropical regions. In contrast, the concentration of Ni found in phyllosilicate clays (mainly smectite/illite) in paddy soils from the temperate regions was only ∼1/4 of that of clay (mainly kaolinite) in the tropical paddy soils, and the ratio of Ni concentration in phyllosilicate clays to highly reactive Fe (hydro)oxides in paddy topsoil in temperate regions was one order of magnitude less than that in tropical regions, which contributes to the low bioavailability of Ni in tropical paddy soils. Furthermore, the accumulation of Ni in rice grains was insensitive to soil pH in tropical regions but showed significant negative correlations with the degree of chemical weathering (chemical index of alteration and index of laterisation) in temperate and tropical regions. These observations support the hypothesis that chemical weathering and the dissolution–recrystallization of Fe (hydro)oxides induced by frequent redox fluctuations in paddy soils cause Ni repartition between Fe (hydro)oxides and phyllosilicate minerals, which influence Ni geochemical cycling and bioavailability, and fundamentally regulate Ni accumulation in rice. This study elucidates the mechanism and controlling factors underlying Ni partition in the basalt-paddy soil-rice plant continuum under distinct climates, providing new insights into the understanding of geochemical behavior and environmental fate of Ni.

Petrography and geochemistry of the Miocene Upper Red Formation sandstones in NW Iran; with an application to the origin and tectonic setting

Middle to Upper Miocene sedimentary successions in the Alborz sedimentary basin (northern Iran) form the caprock of the Lower Miocene gas reservoirs. Their stratigraphic and sedimentological studies have been of interest to geological studies. Due to their importance, in this research, two suitable stratigraphic sections in the Zanjan and Hashtroud regions (northwest of Iran) have been subjected to detailed sedimentological and stratigraphic study to determine the origin and tectonic setting. Clastic-evaporite sediments of the middle to upper Miocene (Upper Red Formation) in the northwest of Iran are about 950 m thick, which is placed on the hydrocarbon reservoirs of the Qom Formation (Lower Miocene) with a discontinuous and abrupt boundary, and are covered by conglomerate and unhardened sediments belong to Pliocene. These sediments in the northwest of Iran are divided into four lithostratigraphic units, including (1) green marls with gypsum, (2) red marls along with gray and red sandstones, (3) red and green marls, and (4) green marls. Based on microscopic studies, the sandstones of this formation are composed of sedimentary and metamorphic rock fragments, quartz, and to a lesser extent, feldspar, pyrite and chlorite, in order of importance. The matrix (carbonate mud) and, to a lesser extent, calcite and evaporite cements form the groundmass of studied sandstones. Based on petrographic studies, these fine-to medium-grained sandstones are litharenite to feldspathic litharenite with an average composition of Q38F13RF49. Also, based on the main constituent components of sandstones and geochemical analysis of major and minor elements, and by drawing different types of separating diagrams, the tectonic setting of these sandstones are considered as an active continental margins and foreland basins (collision belts between Arabia-Eurasia continental plates), which originate from fine-to medium-grained siliceous-clastic rocks, metamorphic, carbonate, and intermediate to felsic igneous rocks outcropped in the region. The data show that these sediments are influenced by arid to semi-arid climate and moderate degree of chemical weathering, mainly from the outcrops of Takab Complex and Qom Formation (Lower Miocene), which have significant outcrops and, to a lesser extent, from Eocene volcanics. The research results are consistent with the paleogeography of the region and previous studies and can be of interest to sedimentologists and other researchers related to petroleum geology.

Geological Characteristics and Paleoenvironmental Evolution of Fine-Grained Sediments in the Third Member of the Xujiahe Formation in the Western Sichuan Depression, SW China

This study investigated, in detail, the characteristics of the Late Triassic fine-grained sediments in the third member of the Xujiahe Formation (Xu-3 Member), in the Western Sichuan Depression, and the paleoenvironmental evolution during their deposition through petrological interpretation, mineralogical composition characterization, and element geochemical analysis. According to the mineralogical composition, the Xu-3 Member can be divided into two petrological types, namely clayey fine-grained felsic sedimentary rocks and lime fine-grained felsic sedimentary rocks. The main mineral components are siliceous, clay, and carbonate minerals. Through the cluster analysis of major elements, all samples could be divided into two types with different major elemental characteristics. Trace elements exhibited distinct Sr depletion, relative enrichment of large ion lithophile elements, and high field strength elements. Two REE enrichment patterns were observed, which could be attributed to differences in the provenance area and tectonic background. The paleoclimate of the sedimentary area was warm and humid, but it was hotter and drier in the southern and central parts of the depression. The change trend of paleo-productivity was consistent with the paleoclimate. The waters in the sedimentary environment were mainly brackish water to saline water, with fresh water in the southern part of the depression. The paleo-redox conditions of the waters were mainly sub-oxidation to sub-reduction, but the southern part of the depression was more oxidative. The provenance area experienced a moderate degree of chemical weathering under a warm and humid paleoclimate, same as the depositional area. However, the depositional environments differed between the northern and south-central parts of the depression.

Tracing the sedimentary provenance of the Mesoproterozoic rocks from Taoudeni Basin (∼ 1.1 Ga) Mauritania: Evidence from Sm/Nd and elemental geochemistry

The Mesoproterozoic era is a crucial period in Earth history characterized by muted oxygen levels in the atmosphere–ocean system. This period is well represented in the non-metamorphosed sedimentary rocks from the Taoudeni Basin, Mauritania. Few studies have been carried out to trace the sources of these sedimentary archives. Here, we examined the sedimentary rocks from the Atar (S4 drill core) and El Mreiti groups (S2 and S3 drill cores). This study focuses on whole-rock elemental geochemistry and Sm/Nd isotope compositions to provide insights into the provenance of the fine-grained siliciclastic sediments from the basal part of the Mesoproterozoic Atar and El Mreiti groups. Paleoweathering indices reveal a moderate degree of chemical weathering in the source areas, consistent with the low compositional maturity of the studied samples. The concentrations of the relatively immobile trace elements suggest mixing sources of sediment provenance, which is dominated by felsic source rocks for the Atar sediments. However, distinctively positive ƐNd(t) values coupled with high 143Nd/144Nd and Sm/Nd ratios and high ƒSm/Nd values of the sediments from the El Mreiti Group indicate derivation from juvenile and less evolved sources rocks. Further, the depleted mantle model ages (TDM) of the provenance protolith (1.95–2.31 Ga) support the argument that the El Mreiti sediments are dominantly sourced from the Paleoproterozoic terrane exposed in the eastern Reguibat Shield while the Atar Group were predominantly from the Archean basement rocks in the western Reguibat Shield. Moreover, Sm/Nd isotope and mixing model results support the major contributions of the felsic Archean rocks of the Reguibat Shield for the Atar Group samples. Although these strata, separated by ∼1000 km, have been described as stratigraphic equivalent, our study demonstrates distinct sediment sources between the Atar Group strata and those of El Mreiti, therefore, reinforcing the importance of sediment provenance in understanding the evolution and reconstruction of modern and ancient sedimentary systems.

Study on the Provenance and Tectonic Setting of Mudstone in the Lower Silurian Longmaxi Formation of the Yanyuan Basin on the Western Margin of the Yangtze Platform

This study investigates the provenance and tectonic background of the lower Silurian Longmaxi Formation black shale of the Yanyuan Basin in the western Kangdian ancient land and provides guidance for shale gas exploration and development in the area. The mineral petrological and geochemical characteristics of the Longmaxi Formation black shale in this area have been studied in detail. The study area is mainly a passive continental margin environment, but also has the attributes of an active continental margin and island arc environment due to the collision between the western oceanic crust and the Yangtze continental crust. The source rocks are mainly felsic igneous rocks, with a small contribution of intermediate–basic rocks. It is inferred that the Kangdian ancient land in the eastern part of the area could be the main provenance area, but with the contribution of sediments derived from oceanic island arc located in the west. During the whole Longmaxi period, the tectonic movement was intense, the climate was cold, the degree of chemical weathering was low, and it was a highly volatile geological sedimentary basin. Therefore, the highly siliceous organic-rich mudstone, which was different from the Sichuan Basin, was deposited.

Climate-induced denudation of the Eastern Ghat during the Holocene: A multi-proxy study from Chilika Lagoon (India)

A Holocene sediment record from Chilika Lagoon, India, suggests that changes in climate control denudation and weathering rate change. We assessed climate variability in the region and through time using multiproxy data comprising biotic and abiotic proxies. Mangrove and its associate assemblages suggest a backwater estuarine environment between ∼7.8 and 6 ka B.P. Depleted δ13Corg values during ∼7.8 to 5.5 ka B.P. indicate dominance of C3 vegetation, suggesting a warmer climate and strengthened monsoon. Enhanced δ13Corg and absence of pollen/spores are observed in the sediment layers deposited after ∼5 ka B.P., indicating arid climatic conditions with a dominance of C4 photosynthesizing plants and a relative lowering of sea level. Paleodenudation rates estimated using 10Be(meteoric)/9Be ratios varied between 556 ± 35 to 242 ± 15 t.km−2.yr−1. Phases of intense denudation occurred during 7.8–6.7 and 2.2–1 ka B.P., corresponding to Holocene Climatic Optimum and Medieval Climatic Anomaly, respectively. The degree of chemical weathering appears to have gradually increased from the early to late Holocene and correlates well (negatively) with the denudation rate. A gradual increase in the degree of chemical weathering from the early to late Holocene suggests an increase in the residence time of minerals in the weathering zone as the monsoon weakened.